Product ID:STRIPING PAINTS-VOC COMPLIANT, 03305 BLOCKOUT BLACK
MSDS Date:01/05/1994
FSC:8010
NIIN:00N070622
MSDS Number: CBMGF

SPRAYON PRODUCTS

31500 SOLON RD
SOLON, OH 44139
US

Emergency Phone: 216-292-7400

Info Phone: 800-777-2966

Cage: DO662

SPRAYON PRODUCTS; SHERWIN WILLIAMS

UNKNOW BEDFORD HEIGHTS, OH 44146

Telephone: 216-292-7400

Cage: DO662

760.

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 18%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

22.

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 23%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9.

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 20%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM;150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

180.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 22%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM;1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)

CAS: 14807-96-6

RTECS: WW2710000

Fraction By Weight: 8%

OSHA PEL 20 MPPCF

ACGIH TLV: 2 MG/M3 RDUST

CALCIUM CARBONATE

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: 18%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 1%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

56% BY WT.

RTECS: 9999999VO

CAN BE HARMFUL/FATAL. ALL PRODS LISTED ON THIS

RTECS: 9999999ZZ

TO CAUSE CANCER, BIRTH DEFECTS & OTHER REPRO HARM.

RTECS: 9999999ZZ

REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH

RTECS: 9999999ZZ

& EXPOSURE INFORMATION .

RTECS: 9999999ZZ

BONDING & GROUNDING PROCS. CONTENTS UNDER PRESS.

RTECS: 9999999ZZ

FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER

RTECS: 9999999ZZ

INTERNALLY. KEEP OUT OF REACH OF CHILDREN. USE ONLY

RTECS: 9999999ZZ

W/SKIN & EYES. THIS COATING MAY CONTAIN MATLS

RTECS: 9999999ZZ

HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED

RTECS: 9999999ZZ

NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 TDUST; OSHA

RTECS: 9999999ZZ

DUST WHICH MAY BE GENERATED FROM THIS PRODUCT,

RTECS: 9999999ZZ

1910.94, 1910.107, 1910.108.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR
PROPER USE, VENT & PERSONAL PROT EQUIP. ACUTE:IRRIT OF EYES, SKIN &
RESP SYS. MAY CAUSE NERV SYS DEP RESS. EXTREME OVEREXP MAY RSLT IN
UNCON& POSSIBLY DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INDICATIONS OF EXCESSIVE EXPOS TO
VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING SENSATION MAY INDICATE
EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY
CAUSE ADVERSE EFTS TO LIVER, URINARY, BLOOD-FORMING, CVS & REPRO
SYS. RATS EXPOS TO TITANIUM DIOXIDE DUST AT 350 MG/M3 DEVELOPED
LUNG (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO
NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL
ATTENTION.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.9%
Upper Limits:34.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS(SUPDAT)
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. CLOSED CONTAINERS
MAY EXPLODE (DUE TO THE BUILD-UP OF PRESSURE) WHEN EXPOSED TO
EXTREME HEAT.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NFPA CODE 30B-LEVEL 1 AEROSOLS. KEEP
AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUMULATE READILY &
MAY IGNITE EXPLOSIVELY. CONSULT NFPA CODE.
Other Precautions:CONTENTS ARE EXTREMELY FLAMM. DURING USE & UNTIL ALL
VAPS ARE GONE:KEEP AREA VENTILATED; DO NOT SMOKE; EXTING ALL
FLAMES, PILOT LIGHTS & HEATERS; TURN OFF STOVES, ELEC TOOLS &
APPLIANCES & ANY OTHER S OURCES OF IGNIT. USE APPRVD (ING 13)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED NIOSH/MSHA APPRVD ORG
VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING
DRIED FILM, WEAR A NIOS H/MSHA APPRVD DUST/MIST RESP FOR(ING 19)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS
MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (ING 20)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN
EXPOS TO EXTREME HEAT. EFTS OF OVEREXP:CANCER, HOWEVER, SUCH EXPOS
LEVELS ARE NOT ATTAINABLE IN WORKPLACE. RPTS HAVE ASSOC RPTD & PRL
NG OVEREXP TO SOLVS W/PERM BRAIN & NERVSYS DMG. INTENTIONAL MISUSE
BY DELIB CONCENTRATING & INHALING CONTENTS (ING 9)

Boiling Pt:B.P. Text:<325F,<163C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>50

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENTS.

Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCIN. DEPRESSURIZE CNTNR.
DISPOSE OF I/A/W FE DERAL, STATE & LOCAL REGS REGARDING POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.